ASTM C1343 – Standard Test Method for Determination of Low Concentrations of Uranium in Oils and Organic Liquids by X-ray Fluorescence
Description:
Significance and Use
5.1 This test method is applicable to organic solutions containing 20 to 2000 μg uranium per mL of solution presented to the spectrometer for the solution techniques or 200 to 50 000 μg uranium per g using the fused pellet technique.
5.2 Either wavelength-dispersive or energy-dispersive XRF systems may be used, provided that the software accompanying the system is able to accommodate the use of internal standards.
Scope
1.1 This test method covers the steps necessary for the preparation and analysis by X-ray fluorescence (XRF) of oils and organic solutions containing uranium. Two different preparation techniques are described.
1.2 The procedure is valid for those solutions containing 20 to 2000 μg uranium per mL as presented to the spectrometer for the solution technique and 200 to 50 000 μg uranium per g for the pellet technique.
1.3 This test method requires the use of an appropriate internal standard. Care must be taken to ascertain that samples analyzed by this test method do not contain the internal standard or that this contamination, whenever present, has been corrected for mathematically. Such corrections are not addressed in this procedure. Care must be taken that the internal standard and sample medium are compatible; that is, samples must be miscible with tri- n-butyl phosphate (TBP) and must not remove the internal standard from solution. Alternatively, a scatter line may be used as the internal standard.2
1.4 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.
ASTM C1436