ASTM D4056 – Standard Test Method for Estimation of Solubility of Water in Hydrocarbon and Aliphatic Ester Lubricants
Description:
Significance and Use
5.1 Knowledge of the water content is important in lubrication, as large amounts of water can cause corrosion fatigue in steel bearings, and the complete absence of water can cause metal scuffing.
5.2 High water content has an accelerating effect on oxidation of lubricants, and can also contribute to foaming, especially at high altitude or temperature, or both.
Scope
1.1 This test method covers a procedure for estimating the equilibrium solubility of water and its vapor in hydrocarbon and aliphatic ester lubricants, at temperatures between 277 K and 373 K. The test method is limited to liquids of low to moderate polarity and hydrogen bonding, with predicted solubilities not over 1000 ppm by weight in hydrocarbons, or 30 000 ppm by weight in oxygenated compounds, at 298 K.
1.2 Specifically excluded are olefins, nitriles, nitro compounds, and alcohols.
1.3 This test method is recommended only for liquids not containing widely different chemical species. This excludes blends of esters with hydrocarbons, and lubricants containing detergents, dispersants, rust preventives, or load carrying additives.
1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.